Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes
Samo za registrovane korisnike
2018
Članak u časopisu (Objavljena verzija)
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Metapodaci
Prikaz svih podataka o dokumentuApstrakt
This study discusses a novel approach for fabrication of floating photocatalyst which can be efficiently exploited for photodegradation of dyes in aqueous solutions. A fabrication of the floating photocatalyst consisted of two steps: transformation of the poly(ε-caprolactone) beads (PCLb) into poly(ε-caprolactone) foam (PCLf) with porous structure in supercritical carbon-dioxide and subsequent loading of PCLf with TiO2 nanoparticles (NPs). Morphological characterization of the PCLf before and after TiO2 NPs loading was carried out by FESEM. The presence of titanium on the surface and inside the PCLf was detected by EDX. Photocatalytical activity of the floating photocatalyst was investigated in aqueous solution of textile dyes C.I. Acid Orange 7 (AO7) and C.I. Basic Yellow 28 (BY28) which were exposed to lamp that simulates the sun light. In addition to sustainable floatability for a long period of time, developed floating photocatalyst exhibited high rate of photodegradation since the... complete discoloration of AO7 and BY28 solutions and photocatalysts alone occurred after 300 and 180 min of illumination, respectively. Its photocatalytic activity was preserved after three repeated photodegradation cycles with unchanged chemical structure that was confirmed by FTIR analysis.
Ključne reči:
TiO2 nanoparticles / Supercritical foaming / Polycaprolactone / Floating photocatalyst / Dye photodegradationIzvor:
Fibers and Polymers, 2018, 19, 6, 1219-1227Izdavač:
- Korean Fiber Society
Finansiranje / projekti:
- Uticaj veličine, oblika i strukture nanočestica na njihova svojstva i svojstva nanokompozita (RS-MESTD-Basic Research (BR or ON)-172056)
- Materijali redukovane dimenzionalnosti za efikasnu apsorpciju svetlosti i konverziju energije (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45020)
DOI: 10.1007/s12221-018-8148-5
ISSN: 1229-9197
WoS: 000437774000009
Scopus: 2-s2.0-85049563576
Institucija/grupa
Institut za opštu i fizičku hemijuTY - JOUR AU - Marković, D AU - Milovanović, S AU - Radovanović, Ž AU - Zizović, I AU - Šaponjić, Zoran AU - Radetić, Maja PY - 2018 UR - https://riofh.iofh.bg.ac.rs/handle/123456789/571 AB - This study discusses a novel approach for fabrication of floating photocatalyst which can be efficiently exploited for photodegradation of dyes in aqueous solutions. A fabrication of the floating photocatalyst consisted of two steps: transformation of the poly(ε-caprolactone) beads (PCLb) into poly(ε-caprolactone) foam (PCLf) with porous structure in supercritical carbon-dioxide and subsequent loading of PCLf with TiO2 nanoparticles (NPs). Morphological characterization of the PCLf before and after TiO2 NPs loading was carried out by FESEM. The presence of titanium on the surface and inside the PCLf was detected by EDX. Photocatalytical activity of the floating photocatalyst was investigated in aqueous solution of textile dyes C.I. Acid Orange 7 (AO7) and C.I. Basic Yellow 28 (BY28) which were exposed to lamp that simulates the sun light. In addition to sustainable floatability for a long period of time, developed floating photocatalyst exhibited high rate of photodegradation since the complete discoloration of AO7 and BY28 solutions and photocatalysts alone occurred after 300 and 180 min of illumination, respectively. Its photocatalytic activity was preserved after three repeated photodegradation cycles with unchanged chemical structure that was confirmed by FTIR analysis. PB - Korean Fiber Society T2 - Fibers and Polymers T1 - Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes EP - 1227 IS - 6 SP - 1219 VL - 19 DO - 10.1007/s12221-018-8148-5 UR - conv_1188 ER -
@article{ author = "Marković, D and Milovanović, S and Radovanović, Ž and Zizović, I and Šaponjić, Zoran and Radetić, Maja", year = "2018", abstract = "This study discusses a novel approach for fabrication of floating photocatalyst which can be efficiently exploited for photodegradation of dyes in aqueous solutions. A fabrication of the floating photocatalyst consisted of two steps: transformation of the poly(ε-caprolactone) beads (PCLb) into poly(ε-caprolactone) foam (PCLf) with porous structure in supercritical carbon-dioxide and subsequent loading of PCLf with TiO2 nanoparticles (NPs). Morphological characterization of the PCLf before and after TiO2 NPs loading was carried out by FESEM. The presence of titanium on the surface and inside the PCLf was detected by EDX. Photocatalytical activity of the floating photocatalyst was investigated in aqueous solution of textile dyes C.I. Acid Orange 7 (AO7) and C.I. Basic Yellow 28 (BY28) which were exposed to lamp that simulates the sun light. In addition to sustainable floatability for a long period of time, developed floating photocatalyst exhibited high rate of photodegradation since the complete discoloration of AO7 and BY28 solutions and photocatalysts alone occurred after 300 and 180 min of illumination, respectively. Its photocatalytic activity was preserved after three repeated photodegradation cycles with unchanged chemical structure that was confirmed by FTIR analysis.", publisher = "Korean Fiber Society", journal = "Fibers and Polymers", title = "Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes", pages = "1227-1219", number = "6", volume = "19", doi = "10.1007/s12221-018-8148-5", url = "conv_1188" }
Marković, D., Milovanović, S., Radovanović, Ž., Zizović, I., Šaponjić, Z.,& Radetić, M.. (2018). Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes. in Fibers and Polymers Korean Fiber Society., 19(6), 1219-1227. https://doi.org/10.1007/s12221-018-8148-5 conv_1188
Marković D, Milovanović S, Radovanović Ž, Zizović I, Šaponjić Z, Radetić M. Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes. in Fibers and Polymers. 2018;19(6):1219-1227. doi:10.1007/s12221-018-8148-5 conv_1188 .
Marković, D, Milovanović, S, Radovanović, Ž, Zizović, I, Šaponjić, Zoran, Radetić, Maja, "Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes" in Fibers and Polymers, 19, no. 6 (2018):1219-1227, https://doi.org/10.1007/s12221-018-8148-5 ., conv_1188 .