Studies of the Thermal and Mechanical Properties of Poly(urethane-siloxane)s Cross-Linked by Hyperbranched Polyesters
Само за регистроване кориснике
2012
Аутори
Dzunuzović, Jasna V.Pergal, Marija V.
Poreba, Rafal
Ostojić, Sanja
Lazić, Nada
Spirkova, Milena
Jovanović, Slobodan
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Polyurethane networks based on Boltorn hyperbranched polyesters (HBPs) of different pseudogenerations as cross-linkers, alpha,omega-dihydroxy(ethylene oxide-poly(dimethylsiloxane)-ethylene oxide) (EO-PDMS-EO) and 4,4'-methylenediphenyl diisocyanate were synthesized using a two-step polymerization reaction in solution. The influence of the pseudogeneration number of Boltorn HBPs on the thermomechanical and thermal properties and morphologies of polyurethane networks was investigated using FTIR, DMTA, TGA, hardness measurements, SEM, and SAXS. Synthesized polyurethanes showed higher cross-linking density and hardness and lower thermal stability with increasing pseudogeneration number of HBP. Samples with lower EO-PDMS-EO content exhibited slightly better thermal stability and higher hardness. All utilized characterization methods yielded consistent results and confirmed the existence of microphase separated morphology with the appearance of certain microphase mixing between segments as t...he pseudogeneration number of HBP increased. The obtained results revealed that the synthesized polyurethanes have good thermal and thermomechanical properties, which can be tailored by changing the pseudogeneration number of the HBP or the EO-PDMS-EO content.
Извор:
Industrial & Engineering Chemistry Research, 2012, 51, 33, 10824-10832Издавач:
- American Chemical Society (ACS)
Финансирање / пројекти:
- Синтеза и карактеризација нових функционалних полимера и полимерних нанокомпозита (RS-MESTD-Basic Research (BR or ON)-172062)
- Czech Science Foundation (GACR) [P108/10/0195]
DOI: 10.1021/ie300927z
ISSN: 0888-5885
WoS: 000307698200010
Scopus: 2-s2.0-84865510522
Институција/група
Institut za opštu i fizičku hemijuTY - JOUR AU - Dzunuzović, Jasna V. AU - Pergal, Marija V. AU - Poreba, Rafal AU - Ostojić, Sanja AU - Lazić, Nada AU - Spirkova, Milena AU - Jovanović, Slobodan PY - 2012 UR - https://riofh.iofh.bg.ac.rs/handle/123456789/243 AB - Polyurethane networks based on Boltorn hyperbranched polyesters (HBPs) of different pseudogenerations as cross-linkers, alpha,omega-dihydroxy(ethylene oxide-poly(dimethylsiloxane)-ethylene oxide) (EO-PDMS-EO) and 4,4'-methylenediphenyl diisocyanate were synthesized using a two-step polymerization reaction in solution. The influence of the pseudogeneration number of Boltorn HBPs on the thermomechanical and thermal properties and morphologies of polyurethane networks was investigated using FTIR, DMTA, TGA, hardness measurements, SEM, and SAXS. Synthesized polyurethanes showed higher cross-linking density and hardness and lower thermal stability with increasing pseudogeneration number of HBP. Samples with lower EO-PDMS-EO content exhibited slightly better thermal stability and higher hardness. All utilized characterization methods yielded consistent results and confirmed the existence of microphase separated morphology with the appearance of certain microphase mixing between segments as the pseudogeneration number of HBP increased. The obtained results revealed that the synthesized polyurethanes have good thermal and thermomechanical properties, which can be tailored by changing the pseudogeneration number of the HBP or the EO-PDMS-EO content. PB - American Chemical Society (ACS) T2 - Industrial & Engineering Chemistry Research T1 - Studies of the Thermal and Mechanical Properties of Poly(urethane-siloxane)s Cross-Linked by Hyperbranched Polyesters EP - 10832 IS - 33 SP - 10824 VL - 51 DO - 10.1021/ie300927z UR - conv_417 ER -
@article{ author = "Dzunuzović, Jasna V. and Pergal, Marija V. and Poreba, Rafal and Ostojić, Sanja and Lazić, Nada and Spirkova, Milena and Jovanović, Slobodan", year = "2012", abstract = "Polyurethane networks based on Boltorn hyperbranched polyesters (HBPs) of different pseudogenerations as cross-linkers, alpha,omega-dihydroxy(ethylene oxide-poly(dimethylsiloxane)-ethylene oxide) (EO-PDMS-EO) and 4,4'-methylenediphenyl diisocyanate were synthesized using a two-step polymerization reaction in solution. The influence of the pseudogeneration number of Boltorn HBPs on the thermomechanical and thermal properties and morphologies of polyurethane networks was investigated using FTIR, DMTA, TGA, hardness measurements, SEM, and SAXS. Synthesized polyurethanes showed higher cross-linking density and hardness and lower thermal stability with increasing pseudogeneration number of HBP. Samples with lower EO-PDMS-EO content exhibited slightly better thermal stability and higher hardness. All utilized characterization methods yielded consistent results and confirmed the existence of microphase separated morphology with the appearance of certain microphase mixing between segments as the pseudogeneration number of HBP increased. The obtained results revealed that the synthesized polyurethanes have good thermal and thermomechanical properties, which can be tailored by changing the pseudogeneration number of the HBP or the EO-PDMS-EO content.", publisher = "American Chemical Society (ACS)", journal = "Industrial & Engineering Chemistry Research", title = "Studies of the Thermal and Mechanical Properties of Poly(urethane-siloxane)s Cross-Linked by Hyperbranched Polyesters", pages = "10832-10824", number = "33", volume = "51", doi = "10.1021/ie300927z", url = "conv_417" }
Dzunuzović, J. V., Pergal, M. V., Poreba, R., Ostojić, S., Lazić, N., Spirkova, M.,& Jovanović, S.. (2012). Studies of the Thermal and Mechanical Properties of Poly(urethane-siloxane)s Cross-Linked by Hyperbranched Polyesters. in Industrial & Engineering Chemistry Research American Chemical Society (ACS)., 51(33), 10824-10832. https://doi.org/10.1021/ie300927z conv_417
Dzunuzović JV, Pergal MV, Poreba R, Ostojić S, Lazić N, Spirkova M, Jovanović S. Studies of the Thermal and Mechanical Properties of Poly(urethane-siloxane)s Cross-Linked by Hyperbranched Polyesters. in Industrial & Engineering Chemistry Research. 2012;51(33):10824-10832. doi:10.1021/ie300927z conv_417 .
Dzunuzović, Jasna V., Pergal, Marija V., Poreba, Rafal, Ostojić, Sanja, Lazić, Nada, Spirkova, Milena, Jovanović, Slobodan, "Studies of the Thermal and Mechanical Properties of Poly(urethane-siloxane)s Cross-Linked by Hyperbranched Polyesters" in Industrial & Engineering Chemistry Research, 51, no. 33 (2012):10824-10832, https://doi.org/10.1021/ie300927z ., conv_417 .