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Solubility in K+-Na+-Mg (4) (2-) aqueous solution at T=298.15 K
dc.creator | Popović, Daniela Z. | |
dc.creator | Miladinović, Jelena | |
dc.creator | Todorović, M. D. | |
dc.creator | Miladinović, Zoran | |
dc.date.accessioned | 2023-06-01T09:37:33Z | |
dc.date.available | 2023-06-01T09:37:33Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 0036-0244 | |
dc.identifier.uri | https://riofh.iofh.bg.ac.rs/handle/123456789/286 | |
dc.description.abstract | In the salt solubility predictions for K+-Na+-Mg (4) (2-) aqueous solution the treatment of thermodynamic data of three-component systems at T = 298.15 K involved the application of the Extended Pitzer's ion-interaction model for the pure and mixed electrolyte solutions and criteria of phase equilibrium. Osmotic coefficients data of three-component systems were revised according to recently published parameters of the solutions NaCl(aq) and KCl(aq) that served as reference standards in isopiestic measurements. Parameters of the extended ion-interaction model of K2SO4(aq) are determined by treatment of experimental and predicted values of osmotic coefficient in supersaturated region obtained by the Zdanovskii-Stokes-Robinson rule. Results of salt solubility prediction were compared to experimental solubility data from literature. The agreement between calculated and experimental solubility data in the systems K2SO4 + MgSO4 + H2O, Na2SO4 + MgSO4 + H2O, and Na2SO4 + K2SO4 + H2O at T = 298.15 K, was excellent. | en |
dc.publisher | Maik Nauka/Interperiodica/Springer, New York | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172063/RS// | |
dc.rights | restrictedAccess | |
dc.source | Russian Journal of Physical Chemistry A | |
dc.subject | solubility | en |
dc.subject | phase equilibrium | en |
dc.subject | osmotic coefficients | en |
dc.title | Solubility in K+-Na+-Mg (4) (2-) aqueous solution at T=298.15 K | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 2186 | |
dc.citation.issue | 13 | |
dc.citation.other | 87(13): 2181-2186 | |
dc.citation.rank | M23 | |
dc.citation.spage | 2181 | |
dc.citation.volume | 87 | |
dc.identifier.doi | 10.1134/S0036024413130219 | |
dc.identifier.rcub | conv_471 | |
dc.identifier.scopus | 2-s2.0-84888150965 | |
dc.identifier.wos | 000326718200011 | |
dc.type.version | publishedVersion |