Single-component panchromatic white light generation, and tuneable excimer-like visible orange and NIR emission in a Dy quinolinolate complex
2021
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Аутори
Mara, DimitrijePilia, Luca
Van de Steen, Maxim
Miletto, Ivana
Zeng, Min
Van Hecke, Kristof
Serpe, Angela
Deplano, Paola
Van Deun, Rik
Artizzu, Flavia
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Panchromatic single-component pure white light generation with a PLQY of similar to 14.5% is obtained from a dysprosium complex with the 5,7-dichloro-8-quinolinol ligand (HClQ) thanks to a peculiar orange-red excimer-like emission induced by pi-staking interactions between discrete dimeric units in the crystal packing. The emission color is highly tunable by phase change and mechanical stimuli. Remarkably, this compound also displays Dy-centered NIR emission at telecommunication wavelengths upon photoexcitation over an extraordinarily broad spectral range.
Извор:
Journal of Materials Chemistry C, 2021, 9, 43, 15641-15648Финансирање / пројекти:
- KU Leuven Postdoctoral Mandate Internal Funds (PDM) [PDM/20/092]
- Research Foundation - Flanders (FWO) [AUGE/11/029, G099319N]
DOI: 10.1039/d1tc04191f
ISSN: 2050-7526
WoS: 000713151900001
Scopus: 2-s2.0-85119284872
Институција/група
Institut za opštu i fizičku hemijuTY - JOUR AU - Mara, Dimitrije AU - Pilia, Luca AU - Van de Steen, Maxim AU - Miletto, Ivana AU - Zeng, Min AU - Van Hecke, Kristof AU - Serpe, Angela AU - Deplano, Paola AU - Van Deun, Rik AU - Artizzu, Flavia PY - 2021 UR - https://riofh.iofh.bg.ac.rs/handle/123456789/772 AB - Panchromatic single-component pure white light generation with a PLQY of similar to 14.5% is obtained from a dysprosium complex with the 5,7-dichloro-8-quinolinol ligand (HClQ) thanks to a peculiar orange-red excimer-like emission induced by pi-staking interactions between discrete dimeric units in the crystal packing. The emission color is highly tunable by phase change and mechanical stimuli. Remarkably, this compound also displays Dy-centered NIR emission at telecommunication wavelengths upon photoexcitation over an extraordinarily broad spectral range. T2 - Journal of Materials Chemistry C T1 - Single-component panchromatic white light generation, and tuneable excimer-like visible orange and NIR emission in a Dy quinolinolate complex EP - 15648 IS - 43 SP - 15641 VL - 9 DO - 10.1039/d1tc04191f UR - conv_964 ER -
@article{ author = "Mara, Dimitrije and Pilia, Luca and Van de Steen, Maxim and Miletto, Ivana and Zeng, Min and Van Hecke, Kristof and Serpe, Angela and Deplano, Paola and Van Deun, Rik and Artizzu, Flavia", year = "2021", abstract = "Panchromatic single-component pure white light generation with a PLQY of similar to 14.5% is obtained from a dysprosium complex with the 5,7-dichloro-8-quinolinol ligand (HClQ) thanks to a peculiar orange-red excimer-like emission induced by pi-staking interactions between discrete dimeric units in the crystal packing. The emission color is highly tunable by phase change and mechanical stimuli. Remarkably, this compound also displays Dy-centered NIR emission at telecommunication wavelengths upon photoexcitation over an extraordinarily broad spectral range.", journal = "Journal of Materials Chemistry C", title = "Single-component panchromatic white light generation, and tuneable excimer-like visible orange and NIR emission in a Dy quinolinolate complex", pages = "15648-15641", number = "43", volume = "9", doi = "10.1039/d1tc04191f", url = "conv_964" }
Mara, D., Pilia, L., Van de Steen, M., Miletto, I., Zeng, M., Van Hecke, K., Serpe, A., Deplano, P., Van Deun, R.,& Artizzu, F.. (2021). Single-component panchromatic white light generation, and tuneable excimer-like visible orange and NIR emission in a Dy quinolinolate complex. in Journal of Materials Chemistry C, 9(43), 15641-15648. https://doi.org/10.1039/d1tc04191f conv_964
Mara D, Pilia L, Van de Steen M, Miletto I, Zeng M, Van Hecke K, Serpe A, Deplano P, Van Deun R, Artizzu F. Single-component panchromatic white light generation, and tuneable excimer-like visible orange and NIR emission in a Dy quinolinolate complex. in Journal of Materials Chemistry C. 2021;9(43):15641-15648. doi:10.1039/d1tc04191f conv_964 .
Mara, Dimitrije, Pilia, Luca, Van de Steen, Maxim, Miletto, Ivana, Zeng, Min, Van Hecke, Kristof, Serpe, Angela, Deplano, Paola, Van Deun, Rik, Artizzu, Flavia, "Single-component panchromatic white light generation, and tuneable excimer-like visible orange and NIR emission in a Dy quinolinolate complex" in Journal of Materials Chemistry C, 9, no. 43 (2021):15641-15648, https://doi.org/10.1039/d1tc04191f ., conv_964 .